Presumably he made capital love (5)
I believe the answer is:
romeo
'presumably he' is the definition.
The definition suggests a singular noun which matches the answer.
'capital love' is the wordplay.
'capital' becomes 'rome' (capital of Italy).
'love' becomes 'o' (love means zero in tennis).
'rome'+'o'='ROMEO'
'made' is the link.
Can you help me to learn more?
(Other definitions for romeo that I've seen before include "He's on the lookout for it?" , "Shakespearean hero" , "Ardent male lover" , "Don Juan" , "Lover boy" .)