Pretty? I couldn't agree more! (5)
I believe the answer is:
quite
'pretty?' is the definition.
('quite' can be a synonym of 'pretty')
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for quite that I've seen before include "Completely -- to some extent" , "Rather" , "Somewhat; fully" , "Somewhat - I agree" , "To a degree" .)