Prince with alluring personality (8)
I believe the answer is:
charming
This could be a double definition.
'prince' is the first definition.
(Prince Charming)
'alluring personality' is the second definition.
'charming' can be an answer for 'alluring' (thesaurus). I'm unsure of the 'personality' bit.
'with' acts as a link.
Can you help me to learn more?
(Other definitions for charming that I've seen before include "Delightful, attractive" , "Lovely! - with 15a" , "Beguiling, enchanting" .)