Principal port of Western Australia (9)
I believe the answer is:
fremantle
'principal port' is the definition.
'fremantle' can be an answer for 'port' (I've seen this before). I am unsure of the 'principal' bit.
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for fremantle that I've seen before include "City serving Perth, Australia as its port" , "Australian port" , "Port near Perth (Australia)" , "port appears" .)