Principal traitors stand up (4)
I believe the answer is:
star
'principal' is the definition.
('star' can be a synonym of 'principal')
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for star that I've seen before include "Symbol of excellence" , "virtuoso" , "Play a leading role" , "feature in film" , "Asterisk" .)