Proper posh bloke and slippery character (7)
I believe the answer is:
genteel
'proper' is the definition.
(thesaurus)
'posh bloke and slippery character' is the wordplay.
'posh bloke' becomes 'gent' (both can mean a man. I am not sure about the 'posh' bit.).
'and' means one lot of letters go next to another.
'slippery character' becomes 'eel' (slippery fish).
'gent'+'eel'='GENTEEL'
Can you help me to learn more?
(Other definitions for genteel that I've seen before include ""Refayned"" , "Artificially polite" , "Exaggeratedly polite" , "Terribly polite" , "Fashionable" .)