Pupil primarily in uniform perhaps to be examined (6)
I believe the answer is:
probed
'be examined' is the definition.
(I've seen this in another clue)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for probed that I've seen before include "Questioned or examined thoroughly and closely" , "Physically examined" , "Did research" , "Investigated closely as dentist does a tooth" , "Examined, dug into" .)