Put on airs behind work counter (6)
I believe the answer is:
oppose
'counter' is the definition.
(I've seen this in another clue)
'put on airs behind work' is the wordplay.
'put on' is a charade indicator (letters next to each other).
'airs' becomes 'pose' (synonyms).
'behind work' becomes 'op' (common abbreviation for 'opus'. I am not sure about the 'behind' bit.).
'pose' after 'op' is 'OPPOSE'.
Can you help me to learn more?
(Other definitions for oppose that I've seen before include "Compete with" , "Counter" , "'Refute, stand against (6)'" , "Argue against" , "face" .)