Queer commander-in-chief, recent appointment (9)
I believe the answer is:
eccentric
'queer' is the definition.
(thesaurus)
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for eccentric that I've seen before include "Bizarre" , "Oddball" , "Unconventionanl or unusual" , "Unconventional or unusual" , "Unconventional, a bit strange" .)