Ray's bottom is starting to get dirty (5)
I believe the answer is:
smear
'dirty' is the definition.
(smearing is a kind of dirtying)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for smear that I've seen before include "Greasy or sticky mark" , "Blot or daub" , "allegation" , "material for examination that is on the slide" , "Spread a greasy or sticky substance over something" .)