Relatives who can be somewhat unstable (5)
I believe the answer is:
aunts
'relatives' is the definition.
(aunt is a kind of relative)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for aunts that I've seen before include "Elderly female relations" , "relatively speaking" , "Relatives get bad US tan" , "Relatives get an odd US tan" , "Parents' sisters" .)