Release head departing BBC (5)
I believe the answer is:
untie
'release' is the definition.
(eg to untie restraints)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for untie that I've seen before include "Let loose" , "Release (knots)" , "resolve" , "Detach" , "Loosen ropes or knots" .)