Religious group a church head set out to form (4)
I believe the answer is:
sect
'religious group' is the definition.
(I've seen this before)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for sect that I've seen before include "Religious faction" , "Denomination" , "party" , "Subdivision of a religion" , "Dissenting clique of a religion" .)