Remove that garment! (5)
I believe the answer is:
shift
I believe this clue is a double definition.
'remove' is the first definition.
(thesaurus)
'that garment' is the second definition.
(shift is a kind of garment)
(Other definitions for shift that I've seen before include "Garment -- period of work" , "Move (fast!)" , "Move; garment" , "Switch" , "Change - period of work" .)