Require little light when irritated (7)
I believe the answer is:
needled
'irritated' is the definition.
(I've seen this before)
'require little light' is the wordplay.
'require' becomes 'need' (synonyms).
'little light' becomes 'led' (abbreviation for light emitting diode. I am not sure about the 'little' bit.).
'need'+'led'='NEEDLED'
'when' is the link.
Can you help me to learn more?
(Other definitions for needled that I've seen before include "bugged" , "Irked" , "Irritated (sl.)" , "Provoked with sewing implement" , "Goaded or provoked" .)