Rich man with time to disrobe (6)
I believe the answer is:
divest
'disrobe' is the definition.
(I've seen this before)
'rich man with time' is the wordplay.
'rich man' becomes 'dives' (I've seen this before).
'with' says to put letters next to each other.
'time' becomes 't'.
'dives'+'t'='DIVEST'
'to' is the link.
(Other definitions for divest that I've seen before include "Rob" , "Deprive, strip" , "Relieve (oneself of garment)" , "disrobe" , "Strip (someone of clothing)" .)