Rower or his headgear (6)
I believe the answer is:
boater
'headgear' is the definition.
(I know that boater is a type of hat)
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for boater that I've seen before include "Sailor's straw hat" , "Stiff hat made of straw" , "Hat; eg, rower" , "Hard flat straw hat, or person on water" , "Flat-topped straw hat" .)