Said Poitier is in southern metropolis (6)
I believe the answer is:
sydney
'metropolis' is the definition.
(I know that Sydney is or was a state capital)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for sydney that I've seen before include "Last Olympic city" , "Largest Australian city" , "Australian city with famous opera house" , "Australian port" , "State capital of New South Wales" .)