Saintly, she has her own place in Merseyside (5)
I believe the answer is:
helen
'saintly she' is the definition.
'Helen' can be an answer for 'she'. I am not certain of the 'saintly' bit.
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for helen that I've seen before include "Trojan war beauty" , "-- Mirren, English actress" , "beautiful woman" , "Her face launched a thousand ships" , "She started Trojan War" .)