Sample artworks latterly stored in gallery (5)
I believe the answer is:
taste
'sample' is the definition.
(I know that sample can be written as taste)
'artworks latterly stored in gallery' is the wordplay.
'latterly' indicates one should take the final letters.
'stored in' indicates putting letters inside.
'gallery' becomes 'tate' (Tate Modern, Tate Britain etc).
The last letter of 'artworks' is 's'.
's' placed within 'tate' is 'TASTE'.
(Other definitions for taste that I've seen before include "Dash" , "style" , "Partake of" , "Sense showing refinement" , "Sample by eating or drinking a little" .)