Saucy hothead somewhere in Scotland (5)
I believe the answer is:
perth
'somewhere in scotland' is the definition.
(Scottish city)
'saucy hothead' is the wordplay.
'saucy' becomes 'pert' (synonyms).
'hothead' becomes 'h' (head letter of 'hot').
'pert'+'h'='PERTH'
(Other definitions for perth that I've seen before include "Western Australia's capital" , "Town at the head of the Tay estuary" , "Australian or Scottish city" , "Capital of Western Australia" , "Home of fair maid" .)