Say yes when willing to do something (5)
I believe the answer is:
ready
'willing to do something' is the definition.
I can't judge whether this definition defines the answer.
'say yes' is the wordplay.
'say' becomes 'read' (synonyms).
'yes' becomes 'y'.
'read'+'y'='READY'
'when' acts as a link.
Can you help me to learn more?
(Other definitions for ready that I've seen before include "All set to go" , "Prompt and adequate" , "Fully-prepared" , "Quick" , "for immediate use" .)