Scent nothing gloomy (5)
I believe the answer is:
odour
'scent' is the definition.
('odour' can be a synonym of 'scent')
'nothing gloomy' is the wordplay.
'nothing' becomes 'o' (looks like zero - 0).
'gloomy' becomes 'dour' (I've seen this before).
'o'+'dour'='ODOUR'
(Other definitions for odour that I've seen before include "Aroma, smell" , "Smell; repute" , "Smell, scent" , "Regard" , "Stench" .)