Second cold chip (5)
I believe the answer is:
shard
'chip' is the definition.
(I've seen this before)
'second cold' is the wordplay.
'second' becomes 's' (common abbreviation).
'cold' becomes 'hard' (both can mean unemotional).
's'+'hard'='SHARD'
(Other definitions for shard that I've seen before
include
"Shell