Seed a mythical door-opener! (6)
I believe the answer is:
sesame
'seed' is the definition.
(sesame seed is a kind of seed)
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for sesame that I've seen before include "Plant cultivated for its seeds - opening word?" , "Seeds used for making oil" , "Plant with edible seeds" , "Open . . . . . . is a magic phrase to gain entry" , "Crop valued for its seeds and oil" .)