Seem offended because British Rail wasn't working? (6)
I believe the answer is:
bridle
'seem offended because' is the definition.
I can't judge whether this defines the answer.
'british rail wasn't working?' is the wordplay.
'british rail' becomes 'br'.
'wasn't working?' becomes 'idle' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'br'+'idle'='BRIDLE'
Can you help me to learn more?
(Other definitions for bridle that I've seen before include "Part of horse's harness that goes on its head" , "Show resentment" , "Horse restraint" , "Bit and reins, etc" , "Part of horse's headgear" .)