Sentimental, having conversely upset companion (5)
I believe the answer is:
crony
'companion' is the definition.
(I've seen this before)
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for crony that I've seen before include "China" , "Intimate companion" , "Close friend" , "mate" , "Sidekick" .)