Separate cape rounded by unpopular revolutionary (6)
I believe the answer is:
detach
'separate' is the definition.
(detaching is a kind of separating)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for detach that I've seen before include "Separate from, remove part" , "Disengage, unfasten" , "Disengage (something) and remove it" , "The reverse of 11 Down" , "Remove from something else, say a coupon" .)