Separated from leader, ran away from Croatian animal (5)
I believe the answer is:
coati
'animal' is the definition.
(mammal of Central and South America)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for coati that I've seen before include "Racoon-like omnivorous creature of Central and South America" , "Raccoon relative" , "South American animal" , "S. and Central American raccoon-like animal" , "Oi cat ! (anag.)" .)