Serene, tranquil (4)
I believe this is a double definition.
'serene' is the first definition.
(synonyms)
'tranquil' is the second definition.
(synonyms)
(Other definitions for calm that I've seen before include "Imperturbable, soothe" , "Still - force 0 on the Beaufort scale" , "Placid and unruffled" , "Peace, tranquillity" , "'After a storm comes a ....'" .)
This clue is a double definition.
'serene' is the first definition.
(similar in meaning)
'tranquil' is the second definition.
(similar in meaning)
(Other definitions for peaceful that I've seen before include "Serene" , "Quiet" , "Calm and undisturbed by strife" , "Not violent" , "Placid, not belligerent" .)