Serene, unruffled (6)
I believe the answer is:
placid
I believe this is a double definition.
'serene' is the first definition.
(synonyms)
'unruffled' is the second definition.
(synonyms)
(Other definitions for placid that I've seen before include "Calm, unruffled" , "Cool and unruffled" , "Calm, peaceful" , "Calm and not easily upset" , "Quiet and still" .)