Serious accent (5)
I believe the answer is:
grave
This clue is a double definition.
'serious' is the first definition.
(both can mean solemn)
'accent' is the second definition.
(I know that grave is a type of accent)
(Other definitions for grave that I've seen before include "Hazardous" , "of importance" , "In which to lay a corpse" , "Sombre in the sepulchre" , "Solemn - burial place" .)