Serpent always wants more, it seems (5)
I believe the answer is:
adder
'serpent' is the definition.
(I know that adder is a type of viper)
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for adder that I've seen before include "Poisonous Brit. snake" , "Venemous snake" , "a poisonous type" , "1 of 21 [SNAKES]" , "Type of snake" .)