She has a way with her (4)
I believe the answer is:
anne
'her' is the definition.
(I've seen this before)
'she has a way' is the wordplay.
'she' becomes 'ann' (I've seen this before**).
'has' means one lot of letters go next to another.
'a way' becomes 'e' (Compass direction - East).
'ann'+'e'='ANNE'
'with' acts as a link.
(Other definitions for anne that I've seen before include "First queen of Great Britain and Ireland" , "- - of Cleves" , "One of the Bronte' tens" , "Second or fourth wife of Henry VIII" , "One of two Henry VIII wives" .)