Sheep that's in natural fibre (5)
I believe the answer is:
ramie
'natural fibre' is the definition.
'ramie' can be an answer for 'fibre' (I've seen this before). I am not sure about the 'natural' bit.
'sheep that's' is the wordplay.
'sheep' becomes 'ram' (male sheep).
'that's' becomes 'ie'.
'ram'+'ie'='RAMIE'
'in' is the link.
Can you help me to learn more?
(Other definitions for ramie that I've seen before include "Tough fibre" , "plant" .)