Shifting angularities — it’s a pain (9)
I believe the answer is:
neuralgia
'pain' is the definition.
(neuralgia is a kind of pain)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for neuralgia that I've seen before include "Sharp pain extending along nerves" , "Acute pain of the nerves" , "Source of pain" , "Pain from damaged nerve" , "sort of pain" .)