Shock as pop falls oddly (5)
I believe the answer is:
appal
'shock' is the definition.
('appal' can be a synonym of 'shock')
'as pop falls oddly' is the wordplay.
'oddly' indicates alternate letters.
'as'+'pop'+'falls'='aspopfalls'
The alternating letters of 'aspopfalls' are 'APPAL'.
(Other definitions for appal that I've seen before include "Greatly horrify" , "Scandalise" , "Greatly dismay" , "Petrify" , "Disgust" .)