Shoe and its buckles, set back on one's heels (10)
I believe the answer is:
astonished
'set back on one's heels' is the definition.
Both the definition and answer are adjectives. Maybe they are linked in a way I don't understand?
'shoe and its buckles' is the wordplay.
'buckles' is an anagram indicator.
'shoe'+'and'+'its'='shoeandits'
'shoeandits' with letters rearranged gives 'ASTONISHED'.
Can you help me to learn more?
(Other definitions for astonished that I've seen before include "dumbfounded" , "given a bombshell?" , "Staggered" , "Taken by surprise" , "Gobsmacked" .)