Show-off hit six to begin with -- I suspect wanting glory primarily? (13)
I believe the answer is:
exhibitionist
'show-off' is the definition.
(someone who shows off)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for exhibitionist that I've seen before include "Attention-seeker" , "Flasher?" , "Show-off" .)