Showing an unusual degree of proclivity to be polite (5)
I believe the answer is:
civil
'be polite' is the definition.
(synonyms)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for civil that I've seen before include "(Of law) non-criminal" , "Nonviolent refusal to obey laws" , "Courteously polite" , "Courteous, polite" , "Polite and non-military" .)