Sign of augmentation (4)
I believe the answer is:
plus
I believe this clue is a double definition.
'sign' is the first definition.
(plus sign is a kind of sign)
'augmentation' is the second definition.
(thesaurus)
'of' is the link.
(Other definitions for plus that I've seen before include "And, arithmetically" , "mark for arithmetic" , "being a little cross" , "And also; a bonus" , "credit" .)