Sign of fear here though singularly daring (6)
I believe the answer is:
nerves
'sign of fear' is the definition.
'nerves' can be an answer for 'fear' (thesaurus). I am not certain of the 'sign of' bit.
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for nerves that I've seen before include "Fibres carrying impulses around the body" , "causing some anxiety" , "Bodily fibres conveying sensations" , "Fibres that convey feelings" , "Apprehensive feeling" .)