Singular thing to shoot in a canoe (5)
I believe the answer is:
rapid
'shoot in a canoe' is the definition.
'rapid' can be an answer for 'shoot' (thesaurus). I am not sure about the 'in a canoe' bit.
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for rapid that I've seen before include "Expeditious" , "Precipitate" , "Happening at great speed" , "Electrical connector" , "Zippy" .)