Siren never has time for leading lady (7)
I believe the answer is:
empress
'for leading lady' is the definition.
(I've seen this before)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for empress that I've seen before include "1 across was from 1877" , "She rules over many territories" , "Catherine the Great, for example" , "Maria Theresa, perhaps" , "Delilah?" .)