Skilful or knowledgeable (6)
I believe the answer is:
expert
This clue is a double definition.
'skilful' is the first definition.
(synonyms)
'knowledgeable' is the second definition.
(thesaurus)
(Other definitions for expert that I've seen before include "At the right moment" , "Specialist, pundit" , "The person who knows" , "Adept" , "Clever" .)