Skilled at limiting vice (5)
I believe the answer is:
adept
'skilled' is the definition.
(similar in meaning)
'at limiting vice' is the wordplay.
'limiting' means one lot of letters goes inside another.
'vice' becomes 'dep' (I am not sure about this - if you are sure you should believe this answer much more).
'at' placed around 'dep' is 'ADEPT'.
Can you help me to learn more?
(Other definitions for adept that I've seen before include "Completely skilled" , "One highly skilled could be taped" , "Highly proficient" , "Proficient - expert" , "Very skilled person" .)