Sly-looking chap (7,3)
I believe the answer is:
peeping tom
'sly-looking chap' is the definition.
I can't judge whether this definition defines the answer.
'looking chap' is the wordplay.
'looking' becomes 'peeping' (peeping is a kind of looking).
'chap' becomes 'tom' (a man's name).
'peeping'+'tom'='PEEPING TOM'
Can you help me to learn more?
(Other definitions for peeping tom that I've seen before include "Spy" , "Voyeur" , "who likes looking at females" , "One who spies pruriently on others" .)