Smart girl dismissing knight (4)
I believe the answer is:
chic
'smart' is the definition.
('chic' can be a synonym of 'smart')
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for chic that I've seen before include "Fashionable good taste" , "A la mode" , "Well turned out" , "cool" , "In vogue" .)