Smooth stuff to intoxicate a saint! (5)
I believe the answer is:
satin
'smooth stuff' is the definition.
'satin' can be an answer for 'smooth' (thesaurus). I am not sure about the 'stuff' bit.
'intoxicate a saint' is the wordplay.
'intoxicate' indicates anagramming the letters (I've seen 'intoxicating' mean this).
'saint' is an anagram of 'SATIN'.
'to' is the link.
Can you help me to learn more?
(Other definitions for satin that I've seen before include "Smooth and silky" , "Rich cloth" , "Stain found in cloth" , "Silky material" , "Stain on shiny fabric" .)