Solitary, single (4)
I believe the answer is:
lone
This clue is a double definition.
'solitary' is the first definition.
(synonyms)
'single' is the second definition.
(synonyms)
(Other definitions for lone that I've seen before include "The ... Ranger, fictional masked cowboy" , "Single and isolated" , "Solitary, without companions" , "He likes to operate by himself" , "Solitary or single" .)